N-(6-Methyl-2-pyridyl)formamide

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N 1,N 2-Bis(6-methyl-2-pyrid­yl)formamidine

In the crystal structure of the title mol-ecule, C(13)H(14)N(4), the two pyridyl rings are not coplanar but twisted about the C-N bond with an inter-planar angle of 71.1 (1)°. In the crystal, the mol-ecules form dimers, situated on crystallographic centres of inversion, which are connected via a pair of N-H⋯N hydrogen bonds. C-H⋯π-electron ring inter-actions are also present in the crystal stru...

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N-(6-Methyl-2-pyrid­yl)formamide

The mol-ecule of the title compound, C(7)H(8)N(2)O, is essentially planar with a maximum deviation of 0.0439 (1) Å from the best plane. In the crystal, N-H⋯O hydrogen bonds between self-complementary amide groups join mol-ecules into centrosymmetric dimers.

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N,N′-Bis(6-methyl-2-pyrid­yl)oxamide

In the crystal structure of the title compound, C(14)H(14)N(4)O(2), the mol-ecules are almost planar (mean deviation 0.028 Å) and a weak intra-molecular N-H⋯O hydrogen bond between the H atom bound to an oxamide N atom and a carbonyl O atom is found. The asymmetric unit consits of one half-mol-ecule which is located on a centre of inversion.

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4-Chloro-N-[N-(6-methyl-2-pyrid­yl)car­bamo­thio­yl]benzamide

In the title compound, C(14)H(12)ClN(3)OS, the short exocyclic N-C bond lengths indicate resonance in the thiourea part of the mol-ecule. The title compound is stabilized by an intra-molecular N-H⋯N hydrogen bond, which results in the formation of a six-membered ring. In addition, it shows a synperiplanar conformation between the thio-carbonyl group and the pyridine group. Inter-molecular N-H⋯S...

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2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide

The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol-ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter-molecular N-H⋯N hydrogen bonds and I⋯O inter-actions link neighbouring mol-ecules into two different pairs of dimers, those involving N-H⋯N interactions having R(2) (...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809053549